XeF 4 Molecular Geometry And Bond Angles. It undergoes sp3d2 hybridization which results in octahedral electron geometry and square planar molecular geometry. The central Xe atom has 4 bond pairs of electrons and two lone pairs of electrons. Back to Molecular Geometries & Polarity Tutorial: Molecular Geometry & Polarity Tutorial. Author has 3.2K answers and 1.4M answer views. Thus, we have octahedral electron pair geometry, and square planar molecular geometry. With this, they will acquire a stable state. With the two lone pairs placed axially opposite to each other, the overall structure of the concerned molecule is symmetric. The geometry of XeF 4 is square planar with symmetric electron region distribution. Xenon Tetrafluoride on Wikipedia. Therefore the shape of XeF4 is square planar. Xenon Tetrafluoride Class: AX(sub)4E2 # of atoms and lone pairs on central atom: 6 # of atoms bonded to central atom: 4 Now if we follow the VSEPR theory, the net electronic repulsions has to be minimum. The geometry of Xeof₄ is square pyramidal. There are six electron pairs around the central atom (Xe), four of which are bonding, and two are lone pairs. VSEPR theory predicts that XeF4 is square planar. It is produced by the chemical reaction of xenon with fluorine, F 2, according to the chemical equation:. Xenon tetrafluoride XeF4 is a planar molecule beonging to the D4h Point group. Xe + 2 F 2 → XeF 4. This reaction is exothermic, releasing an energy of 251 kJ/mol.. Xenon tetrafluoride is a colorless crystalline substance. Therefore this molecule is nonpolar. The molecular polarity is determined by the vector sum (magnitude and … The molecular geometry of XeF4 is square planar. Xenon tetrafluoride is a chemical compound with chemical formula XeF 4.It was the first discovered binary compound of a noble gas. The symmetry operations are shown interactively in 3D What's the electron pair geometry & molecular geometry of XeF4? As we have learned before the s-orbital will be used by the central atom, the hybrid orbitals will be mixed via its p-orbitals … XeF 4 consists of two lone pair electrons.